Record Number: 825
CIS Descriptors: CHEMICAL BURNS
HYDROFLUORIC ACID
CORROSION
INSPECTION
PIPES AND FITTINGS
FIRST-AID TRAINING
FIRST-AID ORGANIZATION
EMERGENCY SHOWERS
PETROCHEMICAL INDUSTRY
PETROLEUM REFINING

FATALITY REPORT



REPORT CHARACTERISTICS:

DONOR: Office of the Chief Coroner
JURISDICTION: Ontario
REPORT TITLE: Verdict of Coroner's Jury
INDIVIDUAL PRESIDING: Dr. K. Flynn, Coroner
PLACE OF INQUIRY: Brampton
DATE OF INQUIRY : 1979-08-08

INFORMATION ABOUT DECEASED:

NAME: Abdul Mirza
OCCUPATION: Unavailable
INDUSTRIAL SECTOR: Petroleum refining industry

ACCIDENT INFORMATION:

DATE OF FATALITY : 1979-05-21
PLACE OF FATALITY: Hamilton General Hospital
BRIEF CAUSE OF DEATH: Severe hypocalcaemia due to fluoride toxicity.
BRIEF MANNER OF DEATH: Received acid burns to his face.
ACCIDENT DESCRIPTION:
While attempting to remove an end plug from a pipe containing 100%
concentration enhydrous hydrofluoric acid under pressure, he applied
sufficient pressure with a wrench to cause a sudden rupture of a pipe
which was severely corroded by acid. The resultant release of acid
under pressure caused the victim's protective hat face shield to fall
off and he received acid burns to his face. He failed to reach a safety
shower immediately and also did not remain under a shower for sufficient
length of time, with the result that severe tissue damage resulted to
the face and absorption of fluoride occurred into his body through this
area. Inhalation of acid vapour may also have occurred. Cardiac arrest
occurred several times in hospital due to depletion of calcium and
magnesium levels in the blood and attempts to correct this situation
were unsuccessful.

RECOMMENDATIONS ISSUING FROM INQUIRY:

Medical care

1. Hospitals and ambulance units in any area to be made aware by industries
of the risk of hazardous substances and their treatment in event of
accident.

2. Flip files to be maintained in emergency departments of hospitals
containing above information, to include names and phone numbers of
industrial physicians and to be regularly reported.

3. Emergency room physicians be provided with full details of industrial
accidents including time, treatment given, and person to contact, to
accompany treatment kit in ambulance.

4. Physicians involved in care of this victim ensure that details of the
case be disseminated in popular medical literature.

Occupational safety

5. An immediate survey and ongoing inspection of all acid-bearing equipment
at Gulf Oil refinery to assess state of corrosion and warn workers of
damaged areas.

6. Joint management/worker program to alert other users of HF Acid to
circumstances of this accident. It is incumbent upon both management
and workers to improve communication with the intention of maintaining
safe working conditions.

7. Safety regulations as already laid down to be prominently displayed at
Gulf Oil.

8. All employees to prove knowledge of relevant safety regulations within
one month of commencing employment.

9. Protective clothing regulations to be enforced.

10. Regular accident drills similar to fire drills, be carried out
routinely.

11. Pipes containing acid to be identified.

12. Shower locations to be prominently posted with suitable lighting,
fluorescent paint etc., and be no further than six meters from any acid
work area.

13. Daily check of shower alarms, radio telephones and stock of neutralizing
solutions.

14. Medical officer or plant nurse to be a member of the safety committee.

15. Control room to be staffed whenever work of any kind is being performed,
at all times and on all shifts.

16. Safety regulations in operators' manual to be placed at the beginning of
the book.

17. Complete written and verbal communication of shift changeover to be
maintained in duplicate.

Occupational health

18. Every employee to prove to medical department that he knows how to
respond to acid exposure to himself and others.

19. Protocol on first aid be displayed prominently at key locations.

20. Supplies of HF neutralizing lotion be kept at key locations checked and
replenished by safety personnel.

21. Wallet cards similar to that used by Allied Chemical to be issued to
every employee, and to include name and phone number of physician
contact.

22. Medical officers in refinery and manufacturing industries to pool their
knowledge and standardize treatment methods.

23. Ministry of Labour, Occupational Health Branch to supervise health and
safety procedures in industrial areas and assist coordination with
medical facilities.

24. Treatment kit available 24 hours a day to accompany victim to the
hospital.







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